钴纳米颗粒的制备及其表征  

Synthesis and Characterization of Cobalt Nanoparticles

作　　者：梁芳[1] 贺加欣[1] 曹先仲[1] 郭林[1] 何林[2] 陈晋平[2] 

机构地区：[1]北京航空航天大学材料科学与工程学院,北京100083 [2]北京大学物理系,北京100871

出　　处：《稀有金属材料与工程》2007年第A02期760-762,共3页Rare Metal Materials and Engineering

基　　金：国家自然科学基金项目;新世纪优秀人才计划(NCET-04-0164)

摘　　要：采用简单的溶液还原方法,以聚乙烯吡咯烷酮(PVP,MW=58,000)作为高分子表面修饰剂,用水合肼(50%)作为还原剂。经回流处理,成功地制备出了分散性较好的钴纳米颗粒。利用XRD、TEM、SQUID等实验方法对产物的形貌、物相及磁性进行了表征。结果表明,产物为六方结构。其饱和磁化强度为153 emu/g,～1.62μB/Co,是体相材料的饱和磁矩的95%,其矫顽力为5174 A·m^(-1)。此方法的优点在于反应条件温和、成本较低,重复性强、产率高且宜于控制。Well-dispersed Co nanoparticles were synthesized successfully by using simple solution reduction method. In this reaction system, PVP serves as surface modified reagent, and hydrazine plays as reduced reagent. The products were characterized by X-ray diffraction （XRD）, scanning electron microscopy （SEM）, transmission electron microscopy （TEM） and superconducting quantum interference device （SQUID） system. The results show that the product was h-Co nanostructure. The saturation magnetization determined at high field is about 153 emu/g, which is roughly 1.62 μB/Co. This amounts to 95% of the bulk value, -1.72 μB/Co, which has a coercivity of-65 Oeat 300 K. The advantages of the method are mild, low-cost, well-repeatable, high-yield and easily controllable

关 键 词：钻纳米颗粒 磁性 溶液还原法 

分 类 号：TB383.1[一般工业技术—材料科学与工程]