硫酸镓催化合成丙酸正丁酯  

Synthesis of n-Butyl Propionate Catalyzed by Gallium Sulfate

作　　者：陈丹云[1] 蔡永伟[1] 

机构地区：[1]河南大学化学化工学院,河南开封475001

出　　处：《食品与药品》2007年第10A期9-10,共2页Food and Drug

基　　金：河南省教育厅自然科学研究项目(2004601042);河南省教育厅自然科学计划项目(200510475015)。

摘　　要：目的研究硫酸镓在合成丙酸正丁酯工艺中的催化性能。方法考察硫酸镓用量、醇酸物质的量比、反应时间及催化剂重复使用次数等因素对收率的影响。结果硫酸镓催化活性高,易分离回收,操作简单,后处理方便,重复使用性良好。最佳反应条件下收率为86.03%。结论硫酸镓是合成丙酸正丁酯的良好催化剂。Objective To study the catalytic activity of gallium sulfate in the synthesis of n-butyl propionate. Methods The effects of amount of gallium sulfate, molar ratio of alcohol to acid, reaction time and repeated times of catalyst on the yield of n-butyl propionate were investigated. Results Gallium sulfate had high catalytic activity and could be recovered easily, operated simply, post-treated conveniently and used repeatedly. Under the best conditions, the yield of n-butyl propionate could reach 86.03%. Conclusion Gallium sulfate is an excellent catalyst for the synthesis of n-butyl propionate.

关 键 词：丙酸正丁酯 硫酸镓 催化 合成 

分 类 号：O623.624[理学—有机化学]