过氧化氢环氧化丙烯制环氧丙烷的研究新进展  

Research progress in reaction of propylene epoxidation with hydrogen peroxide

作　　者：史春风[1] 朱斌[1] 林民[1] 龙军[1] 

机构地区：[1]中国石化石油化工科学研究院,北京100083

出　　处：《现代化工》2007年第9期17-21,共5页Modern Chemical Industry

基　　金：国家重点基础研究"973"资助项目(2006CB202508)

摘　　要：综述了过氧化氢与丙烯环氧化反应的研究新进展,主要包括商品过氧化氢与丙烯环氧化、过氧化氢制备与丙烯环氧化的集成、氢氧原位一步法丙烯环氧化的研究。并分析了我国环氧丙烷生产面临的挑战,指出我国环氧丙烷清洁生产势在必行,国内研究应立足环境友好新工艺,关键是高活性、高选择性催化剂的开发。The new research progress in epoxidation of propylene with hydrogen peroxide as an oxidant, including propylene el）oxidation with hydrogen peroxide for sale, process integration for propylene epoxidation and hydrogen peroxide production, and propylene epoxidation with hydrogen peroxide in-sire synthesized in the presence of hydrogen and oxygen. The challenge in propylene oxide production in China is also analysed. It is indicated that cleaner production of propylene oxide be imperative under the situation and the domestic research should be based on the environmental benign process, while the key is to develop highly active and selective catalysts.

关 键 词：环氧丙烷 丙烯 环氧化 过氧化氢 

分 类 号：TQ032.4[化学工程]