固体催化剂催化合成丙酸正丁酯  

Synthesis of n-Butyl Propionate Catalyzed by Solid Catalyst

作　　者：游沛清[1] 文瑞明[1] 俞善信[2] 

机构地区：[1]湖南城市学院,益阳413000 [2]湖南师范大学化学化工学院,长沙410081

出　　处：《精细石油化工进展》2007年第9期25-29,共5页Advances in Fine Petrochemicals

基　　金：湖南省科技计划资助项目(06FJ3197);2007年益阳市科技计划资助项目

摘　　要：综述了对甲苯磺酸、十二烷基磺酸铁、磺化苯膦酸锆、氨基磺酸、强酸性阳离子交换树脂、三氯化铁、四氯化锡、氯化亚锡、无机氯化物、树脂固载Lewis酸、水合硫酸铁、十二水合硫酸铁铵、硫酸钛、铁钾盐、季铵盐、固体超强酸、杂多酸和分子筛等固体催化剂催化合成丙酸正丁酯的实验结果。结果表明,对甲苯磺酸、十二烷基磺酸铁、强酸性阳离子交换树脂等作催化剂合成丙酸丁酯收率较高,具有实际应用价值。The catalytic synthesis of n - butyl propionate using solid catalyst such as p - toluene sulfonic acid, ferric tri（dedecane sulfonate）, zirconium sulpho- phenylphosphonate, aminosulfonic acid, strongly acidic cationic exchange resin, chloride, starmic chloride, stannous chloride, inorganic chlorides, resin support Lewis acid, zinc sulfate, ferric sulfate hydrate, ammonium ferric sulfate dodecahydrate, sodium bisulfate, quaternary ammonium salt, solid supper acid, heteropolyacid and molecular sieve were reviewed. It showed that super acid resin p - toluene sulfonic acid, D001 -AlCl3 ,the strongly acidic cation exchange resin and aminosulfonic acid are excellent catalysts for synthesis of n - butyl propionate with higher yields and practical application value.

关 键 词：丙酸正丁酯 固体催化剂 丙酸 正丁醇 酯化反应 

分 类 号：TQ225.24[化学工程—有机化工] TQ655