N,N’-二苯基-N,N’-二(2-菲基)-4,4’-联苯二胺的合成及结构表征  

Synthesis and characterization of N,N'-diphenyl-N,N'-di(2-phenanthryl)-4,4'-benzidine

作　　者：周袭非[1] 魏冰[2] 王勇[1] 王伟[1] 

机构地区：[1]辽宁科技大学化工学院,鞍山114051 [2]大连理工大学化工学院,大连116023

出　　处：《化工新型材料》2007年第9期48-49,共2页New Chemical Materials

基　　金：辽宁省自然科学基金(20022165)

摘　　要：以二苯胺和菲为初始原料,合成了空穴传输层材料N,N’-二苯基-N,N’-二(2-菲基)-4,4’-联苯二胺。并用红外光谱、核磁共振谱、元素分析对其结构进行了表征。对反应的工艺条件进行了优化,优化反应条件为邻二氯苯为反应体系的较佳溶剂,相转移催化剂TBAB的质量分数为4.5%。Hole-transmission material N, N＇-diphenyl-N, N＇-di （ 2-phenanthryl）-4, 4＇-benzidine was synthesized from diphnylamine and phenanthrene. The structures were characberized by IR＇^1HNMR and elemental analysis. The factors of affecting reaction were studied. The reaction parameters were optimized as follows： o-dichlorobenzene as solvent phase transfer catalyst TAAB was 4.5%. Under these conditions the yield was up to 68. 9%.

关 键 词：二苯胺 菲 空穴传输层材料 合成 表征 

分 类 号：TQ246.31[化学工程—有机化工]