酚醛改性脂肪胺环氧树脂固化剂的性能研究  被引量:3

Research on phenol and aldehyde-modified aliphatic amine as epoxy resin curing agent

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作  者:马诗纬[1] 王钧[1] 段华军[1] 杨青海[1] 

机构地区:[1]武汉理工大学材料科学与工程学院,湖北武汉430070

出  处:《粘接》2007年第5期8-10,共3页Adhesion

摘  要:用酚醛改性脂肪胺(乙二胺、二乙烯三胺)与聚醚胺作为混合固化剂固化环氧树脂,研究了聚醚胺的用量对环氧树脂凝胶时间、冲击韧性以及粘接性能的影响;并通过测试钢-钢拉剪强度研究了此结构胶粘剂的耐湿热老化性能。实验结果表明,随着聚醚胺用量的增加,环氧树脂固化体系的凝胶时间增长,树脂浇铸体的冲击韧性明显提高,粘接强度先提高再降低,最高值达到16.2 MPa;随着湿热老化时间的增加,环氧树脂固化体系的粘接性能逐渐降低。Using the mixture of phenal and aldenhyde-modified ethylene diamine or diethylenetriamine and amine-terminated polyether as the curing agent . this paper studied the influence of the amount of amine-terminated polyether on gel time, impact toughness and bonding performance of epoxy resin. Through steel-steel bonding test the hydrothermal ageing performance of the struetual adhesive was studied. The test results showed that with increasing of the amount of amine-terminated polyether, the gel time was longer, the impact intensity was larger and the bonding strength was increasing at first and then decresing, the maximum value reached 16.2 MPa ; with increasing of hydrothermal ageing time, the bonding properties of cured epoxy resin was gradually decreased.

关 键 词:聚醚胺 环氧树脂 改性乙二胺 改性二乙烯三胺 

分 类 号:TQ433.437[化学工程] TQ314.256

 

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