不同表面活性剂对纳米ZnO/ZrO_2的制备和脱硫性能的影响  

Influence of Different Surface Active Agents on the Preparation of Nanometer ZnO/ZrO_2 and the Desulphurization Properties

作　　者：顾华志[1] 汪慧峰[1] 汪厚植[1] 汪姣[1] 

机构地区：[1]武汉科技大学耐火材料与高温陶瓷省部共建国家重点实验室培育基地,武汉430081

出　　处：《人工晶体学报》2007年第3期642-645,共4页Journal of Synthetic Crystals

基　　金：湖北省自然科学基金资助项目(No.2003ABA079)

摘　　要：研究不同表面活性剂对采用共沉淀-真空冷冻干燥法制备的ZnO/ZrO2纳米催化剂的结构和物相变化的影响,并在模拟烟气中利用气相色谱仪进行脱除SO2性能的测定。结果表明,表面活性剂的引入可以降低纳米ZrO2的平均晶粒度。与吐温80、PEG-400和PVA相比,柠檬酸铵和DBS抑制晶核生长的能力更大,从而纳米ZrO2的平均晶粒尺寸更小,脱硫率更高;由于PEG-400具有络合正离子的能力,可防止纳米活性组分的团聚和长大,其催化吸收SO2的性能最好。The influence of different surface active agents on phase and structure of nanometer ZnO/ZrO2 catalyst prepared by co-precipitation-vacuum drying method has been investigated in the paper, and the desulphurization properties of the catalyst has been measured by gas chromatograph in simulated flue gas. I The results show that the addition of surface activators can reduce the average crystal grain size of nanometer ZrO2. Comparing with surface active agents Tween 80, PEG-400 and PVA, ammonium citrate and DBS can restrain the germination of crystal grain more efficiently, then the average grain size of nanometer ZrO2 is smaller and the desulphurization rate is higher; since the surface active agent PEG-400 has the ability to complexate positive ion which can prevent nanometer active components from agglomerating and growing up, so the catalytic absorption for SO2 is the best.

关 键 词：纳米材料 氧化锌 氧化锆 表面活性剂 分散 脱硫 

分 类 号：TB332[一般工业技术—材料科学与工程]