直线法研究Ni[i-(C_3H_7O)_2PS_2]_2与1,10-菲啰啉的加合反应  

Studay on Adductive Reaction of Ni[i-(C_3H_7O)_2PS_2]_2 with 1,10-phenanthroline by Straight Line Method

作　　者：刘照文[1] 贺敏强[2] 

机构地区：[1]宿迁学院材料科学与工程系,江苏宿迁223800 [2]江苏大学化学化工学院,江苏镇江212003

出　　处：《大庆师范学院学报》2007年第5期119-121,共3页Journal of Daqing Normal University

摘　　要：用P2S5、i-C3H7OH和NiCl2.H2O为原料合成了(Ni[i-(C3H7O)2PS2]2),光谱法研究了它与1,10-菲啰啉的加合反应,并应用直线法确定此加合反应的稳定常数为8.24×107和加合物组成比为1∶2。（ Ni[i - （ C3H7O）2PS2 ] 2 ） has been synthesized with P2S5, i - C3H7OH and NiCl2· H2O.The adductive reaction of Nil[i -（ C3H7O）2 PS2 ]2 with 1,10- phenanthroline is studied by spectrophotometer method. By staight line method, stablity constants of the adductive reaction is 8.24 × 10^7 , and composite ratio of the compound is 1：2.

关 键 词：1 10-菲哕啉 直线法 平衡常数 组成比 

分 类 号：O623.627[理学—有机化学]