Uron环结构化合物的合成与稳定性研究  被引量:2

Study on Composition of Uron Rings and Its Stability

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作  者:田雨[1] 刘亚青[1] 赵贵哲[1] 孙友谊[1] 曹杨[1] 朱福田[1] 

机构地区:[1]中北大学材料科学与工程学院,太原030051

出  处:《绝缘材料》2007年第5期19-21,25,共4页Insulating Materials

基  金:山西省科技攻关项目(033004);山西省科技成果推广项目(200671037)

摘  要:在弱碱性条件下,以尿素和多聚甲醛为原料进行加成反应合成Uron环结构化合物。利用^13CNMR、FTIR研究弱碱性环境下产物结构特征。结果表明:多聚甲醛在弱碱性条件下尿素的取代主要以多取代为主,产物中有高含量的Uron环结构存在。环境温度为25℃,pH值为8~9时,产物稳定性好、贮存期长、游离甲醛含量低;DSC-TG结果表明产物有较好的热稳定性,适合后续反应。Under the alkalescency condition, Uron rings compound was synthesized by the addition re- action with paraformaldehyde and urea as materials. The characteristic of structure formation of the product synthesized under the alkalescency condition was analyzed by ^13CNMR and FTIR methods. The results show that the urea is reacted by multi-replacement in the process of paraformaldehyde under the alkalescency condition; and high content of Uron rings exists in the product. Under the conditions of 25 12 ambient temperature and a pH value of 8-9, the product can be stored for a long time with good stability and low extricate formaldehyde. The result of DSC-TG indicates that the product has better thermo stability and adapts to succeeding reaction.

关 键 词:尿素 多聚甲醛 Uron环化合物 

分 类 号:TQ323.3[化学工程—合成树脂塑料工业]

 

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