新型结构的多官能团单体敏化交联聚丙烯的研究  

THE EFFECT OF A NEW POLYFUNCTIONAL MONOMER ON THE RADIATION CROSSLINKING OF POLYPROPYLENE

作　　者：杨慧丽[1] 刘长海[1] 徐俊[1] 

机构地区：[1]中国科学院长春应用化学研究所

出　　处：《辐射研究与辐射工艺学报》1997年第2期96-99,共4页Journal of Radiation Research and Radiation Processing

摘　　要：合成了一种新型结构的多官能团单体Ｎ，Ｎ＇－双（４，６－二烯丙氧基－均三嗪－２－）１，１０－癸二胺，利用红外光谱和元素分析对其结构进行了表征。将其与聚丙烯共混后长时间放置不出现发烟和“冒汗”现象。A new polyfunctional monomer (PFM), N,N-bis (4,6-diallyloxy-triazinyl-2-)1,10-decanediamine was synthesized. Its structure was confirmed by IR spectroscopy and element analysis. Little smoke was observed when this PFM was kneaded with polypropylene (PP) on a two-roll mill, it didn't ooze out to the sheet sample surface after a long storage time, and the crosslinking of PP byγ-irradiation was notably sensitized.

关 键 词：多官能团单体 辐射交联 聚丙烯 敏化效应 

分 类 号：O632.12[理学—高分子化学] TQ316.64[理学—化学]