微孔氟化磷酸镓Ga_3P_3O_(12)F·0.5(1,8-C_8H_(22)N_2)的水热自组装与晶体结构(英文)  

Self-assembly and Crystal Structure of Microporous Fluorogallophosphate Ga_3P_3O_(12)F·0.5(1,8-C_8H_(22)N_2) under Hydrothermal Conditions

作　　者：杨玉林[1] 胡伟[1] 刘新荣[1] 李琳[1] 姜兆华[1] 

机构地区：[1]哈尔滨工业大学材料科学与工程学院应用化学系,哈尔滨150001

出　　处：《人工晶体学报》2007年第5期1035-1038,共4页Journal of Synthetic Crystals

基　　金：The project supported by the National Natural Science Foundation of China(No.20671025);Department of Education Foundationof Heilongjiang Province( No.10551335);the Natural Science Foundation of Heilongjiang Province ( No.13200603);Harbin Science and Technolongy Bureau Foundation of China(No.2005AFXXJ034)

摘　　要：采用水热合成法制备了一个三维微孔氟化磷酸镓Ga3P3O12F.0.5(1,8-C8H22N2)(简称Hit-6)。反应起始原料摩尔配比为:GaOOH:H3PO4:HF:1,8-辛二胺:H2O=1:2:1:1:555。Hit-6的骨架是由Ga3P3六聚体结构单元通过共顶点联接构成三维纳米孔结构,在[101]方向呈现8-元环孔道。A three-dimensional microporous fluorogallophosphate Ga3P3O12F·0.5（1,8-C8H12N2） （named Hit-6） was synthesized from self-assembly of simple mixture under the mild hydrothermal conditions. The molar ratio of the initial raw mixture was GaOOH：H3PO4：HF：1 8-diaminooctane：H2O=1：2：1：1：555. The 3-D anionic framework of Hit-6 is constructed from Ga3P3 hexamer structural units. Ga3P3 structural units are linked by vertex-sharing to form a 3-D nanoporous material with 8-ring channels along the [101] direction.

关 键 词：水热合成 微孔 氟化磷酸镓 晶体结构 

分 类 号：O76[理学—晶体学]