二苯甲醇结构异构体在胶束纸色谱分离中的反键合行为  

Antibinding Behaviour of Diphenylmethyl Alcohols' Structural Isomers on Micellar Paper Chromatographic Separation

作　　者：蔡俊[1] 付正生[2] 王晓峰 

机构地区：[1]西北民族学院预科部,兰州730030 [2]西北师大化学系,兰州730030

出　　处：《西北民族学院学报（自然科学版）》1997年第1期24-27,共4页Journal of Northwest Minorities University(Natural Science )

基　　金：甘肃省教委科研基金资助

摘　　要：二苯甲醇结构异构体以十二烷基硫酸钠胶束水溶液为展开剂,在纸色谱分离中的保留行为不仅偏离Armstrong标准曲线,而且是反键合型的。其原因在于立体效应,溶质的分子结构和胶束的形状与大小能否适配是色谱分离的主要驱动力。其机理仍然符合Armstrong理论。The retention behaviour in the separation of diphenylmethyl alcohols'structural isomers using aqueous sodium dodecylsulfate micellar mobile phase by paper chromatography not only deviates considerably from the ideal Armtrong curve, but also indicates antibinding behaviour which is due to the steroscopic effect. The suitability of the relationship between the solutes' molecular structures and the micellar shapes and sizes is the main driving force of chromatographic separation. Its mechanism still conforms to the Armstrong theory.

关 键 词：二苯甲醇 异构体 胶束纸色谱 反键合型 分离 

分 类 号：O625.34[理学—有机化学]