键联法合成高分子负载金属卟啉催化剂的研究进展  

The synthesis strategies of macromolecule-supported metalloporphyrin catalysis by chemical bonding

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作  者:陈鲜丽[1] 

机构地区:[1]韶关学院医学院,广东韶关512026

出  处:《韶关学院学报》2007年第9期86-88,共3页Journal of Shaoguan University

基  金:国家自然科学基金(20071034);广东省自科学基金(021726).

摘  要:高分子负载金属卟啉有望提高金属卟啉的催化活性和稳定性,能有效地与产物分离,因此成为研究的热门课题.综述了近年来以静电作用、轴向配位和共价键合成高分子负载金属卟啉催化剂的研究进展.以金属卟啉单体与其他单体共聚合成高分子负载金属卟啉催化剂有望成为新的热门课题.Much attention has been paid to the synthesis and studies of catalysis capability of macromolecule - supported coordination compounds because they have higher catalytic activities and stability and are easily separated from productions. Much research has made to chemical modification of tiny spheric macmmolecule by bonding metalloporphyrin to the surface of sphere but few was reported by polymerizing monomers of metaUoporphyrin and others in the sdudies of macroroolecule-supported metalloporphyrin. The later will be another pop theme.

关 键 词:高分子负载 金属卟啉 催化 

分 类 号:O643.3[理学—物理化学]

 

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