巯基卟啉自组装膜的制备及应用研究进展  

Preparation and Development of Thiol-derivatized Porphyrins Self-Assembled Monolayers

作　　者：杨建东[1] 原慧卿[1] 李秀娟[1] 卢小泉[1] 

机构地区：[1]西北师范大学化学化工学院,兰州730070

出　　处：《分析化学》2007年第11期1679-1684,共6页Chinese Journal of Analytical Chemistry

基　　金：国家自然科学重点基金(No32335030);国家自然科学基金(No20225060);教育部第四届高校青年教师教学科研奖励计划(TRAPOYT);电分析化学国家重点实验室(中科院长春应化所)开放课题基金;西北师范大学科技创新工程(NoKJCX201)资助项目

摘　　要：详细介绍了巯基卟啉自组装膜的几种制备方法,评述了不同制备方法的优缺点;对卟啉自组装膜在电荷转移、分子氧电催化、分子光电器件等领域的研究进展进行了评述,引用文献54篇。Several methods of prepareing thiol-derivatized porphyrin self-assembled monolayers （SAMs） have been comprehensively introduced with 54 references. Both advantages and disadvantages of preparation of thiol-derivatized porphyrins SAMs are also described. Recent advances on the study, that thiol-derivatized porphyrins SAMs in the electrical transfer, electrocatalytic reduction of dioxyen and molecular photovohaic devices, have been discussed.

关 键 词：巯基卟啉 自组装膜 电子转移 分子氧电催化 分子光电器件 评述 

分 类 号：O626[理学—有机化学]