Effects of Al partial substitution for Ni on properties of LaNi_(5-x)Al_x  

作　　者：曹大力 程宏辉 马雷 陈德敏 吕曼祺 杨柯 

机构地区：[1]School of Materials Science and Engineering,Shenyang Institute of Chemical Technology [2]Institute of Metal Research,Chinese Academy of Sciences

出　　处：《中国有色金属学会会刊：英文版》2007年第A02期967-971,共5页Transactions of Nonferrous Metals Society of China

基　　金：Project (50276063) supported by the National Natural Science Foundation of China

摘　　要：The hydrogen storage properties of four LaNi5-xAlx(x = 0.25,0.50,0.75,1.00) pseudobinary alloys were systematically studied. The characteristics of microstructure before and after hydrogenation,activation,kinetics and thermodynamics properties,as well the anti-combustibility properties of the four pseudobinary alloys were investigated. The results reveal that the alloys have excellent activation properties and kinetics properties. X-ray diffraction analysis of crystal lattice of the alloys show that the crystal structures of alloys do not change with the addition of Al in the range of 0≤x≤1,but the lattice constants slightly increase. It is found by measuring thermodynamic properties of the alloy-H2 systems that with increasing x value the equilibrium pressure,hydrogen-absorbing ability and hysteresis decrease,whereas the absolute value of the enthalpy increases. It is also found that the hydrogen absorbing velocity of the alloys decreases with increasing x value.The hydrogen storage properties of four LaNi5-xAlx （x=0.25, 0.50, 0.75, 1.00） pseudobinary alloys were systematically studied. The characteristics of microstructure before and after hydrogenation, activation, kinetics and thermodynamics properties, as well the anti-combustibility properties of the four pseudobinary alloys were investigated. The results reveal that the alloys have excellent activation properties and kinetics properties. X-ray diffraction analysis of crystal lattice of the alloys show that the crystal structures of alloys do not change with the addition of AI in the range of 0≤x≤ 1, but the lattice constants slightly increase. It is found by measuring thermodynamic properties of the alloy-H2 systems that with increasing x value the equilibrium pressure, hydrogen-absorbing ability and hysteresis decrease, whereas the absolute value of the enthalpy increases. It is also found that the hydrogen absorbing velocity of the alloys decreases with increasing x value.

关 键 词：储氢合金 性能 铝 镍 

分 类 号：TG139.7[一般工业技术—材料科学与工程]