D_3-三高立方烷亚甲基上引入硝基的新方法  

A New Method for Introducing Nitro Group into the Secondary Carbons of D3-Trishomocubane

作　　者：管晓培[1] 于永忠[1] 阎红[2] 孙莉[2] 

机构地区：[1]北京理工大学化工与材料学院,100081 [2]北京工业大学化学与环境工程学系,100022

出　　处：《北京工业大学学报》1997年第2期99-101,共3页Journal of Beijing University of Technology

摘　　要：报道了一种在D_(3-)三高立方烷亚甲基上引入硝基的新方法.应用改进的维克托-迈耶反应,成功地将D_(3-)三高立方烷-4,7-二醇(1)最终转化为4,7-二硝基D_(3-)三高立方烷(3);将原有方法的五步反应缩短为两步反应,并将总得率由低于15%提高到近30%.A new method for introducing nitro group into the secondary carbons of D3-trishomocubane is reported. D3-Trishomocubane-4,7-diol(1) was successfully converted into 4,7-dinitro-D3-trishomocubane (3) by modified Victor-Mayer Reaction. The total yield was increased from 15% to 30% while the previous required 5 steps was reduced to 2 steps.

关 键 词：硝基 亚甲基 三高立方烷 V-M反应 重排 

分 类 号：O624.6[理学—有机化学]