超临界二氧化碳介质中钯催化的一些交叉偶联反应的研究  

Cross-Coupling Reactions Catalyzed by Palladium in Supercritical Carbon Dioxide

作　　者：张涛[1] 冯秀娟[1] 王春霞[1] 包明[1] 

机构地区：[1]大连理工大学精细化工国家重点实验室,大连116012

出　　处：《有机化学》2007年第12期1463-1472,共10页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.20603005)资助项目

摘　　要：构建新的C—C键,在有机合成中占有非常重要的地位;超临界二氧化碳,作为环境友好的有机反应介质,已引起人们的广泛关注.综述了近年来超临界二氧化碳介质中钯催化的C—C键形成反应的研究进展,包括Heck,Suzuki,Stille和Sonogashira反应等.The construction of new carbon-carbon bond is very important in organic synthesis. The supercritical carbon dioxide has attracted considerable attention because it can be used as an environmentally benign medium for organic reactions. In this paper, palladium catalyzed cross-coupling reactions to form new carbon-carbon bond including Heck reaction, Suzuki reaction, Stille reaction as well as Sonogashira reaction, proceeded in supercritical carbon dioxide are reviewed.

关 键 词：超临界二氧化碳 钯催化 C—C键形成反应 

分 类 号：O643.32[理学—物理化学]