几种新型超分子配合物的合成和表征  

Syntheses and characterizations of several new supramolecular coordination compounds

作　　者：李胜利[1] 郁建华[1] 杨捷[1] 马文[1] 吴杰颖[1] 

机构地区：[1]安徽大学化学化工学院,安徽合肥230039

出　　处：《安徽大学学报（自然科学版）》2007年第6期62-65,77,共5页Journal of Anhui University(Natural Science Edition)

基　　金：国家自然科学基金资助项目(50532030);安徽省教育厅自然科学基金资助项目(2005KJ101)

摘　　要：制备3种新型超分子配合物并运用常规方法进行表征,讨论配体的特征骨架、空间配位方式和氢键作用对超分子形成的影响.以实验证实,从分子设计,通过分子自组装,是合成具有超分子结构配合物的有效途径.同时培养出化合物的高质量单晶,解析了晶体结构,分析和探讨了超分子配合物的组成-结构-性质之间的关系.Three new supramolecular coordination compounds containing thiosemicarbazide have been synthesized via molecular design and spontaneous assembly. Their single crystals have been obtained and the complexes have been characterized by various ways. The composition- structure -characterization relationships are discussed in this thesis. This research work has been carried out in order to design and synthesize new functional supramolecular complex with novel structure more effectively.

关 键 词：超分子 配合物 合成 结构 

分 类 号：O635[理学—高分子化学]