1-(2-吡啶偶氮)-2-萘酚分子印迹聚合物的制备及结合特性研究  

Study of Preparation and Binding Characteristics of Molecularly Imprinted Polymers for 1-(2-Pyridylazo)-2-naphthol

作　　者：张茂升[1] 黄佳蓉[1] 魏长麟[1] 余彬彬[2] 

机构地区：[1]漳州师范学院化学与环境科学系,福建漳州363000 [2]厦门大学化学化工学院化学系现代分析科学教育部重点实验室,福建厦门361005

出　　处：《分析科学学报》2007年第6期655-659,共5页Journal of Analytical Science

基　　金：福建省教育厅科技项目(No.JA07156)

摘　　要：以α-甲基丙烯酸为功能单体,在氯仿溶剂中,利用传统的分子印迹聚合物制备技术,成功合成了偶氮类分子1-(2-吡啶偶氮)-2-萘酚的印迹聚合物。用红外光谱、紫外光谱等技术对聚合物进行了表征测定,并用平衡结合实验研究了聚合物的吸附特性。A molecularly imprinted polymer, 1-（2-pyridylazo）-2-naphthol, was synthesized with α-acrylic acid as a functional monomer in the chloroform solvent by classical molecularly imprinted technique. The polymer was characterized by IR, UV spectra and the equilibrium binding experiment. The adsorption capability and adsorption kinetics of the polymer was investigated in the study. The results showed that the molecularly imprinted polymer is highly selective to 1-（2-pyridylazo）-2-naphthol.

关 键 词：分子印迹技术 吸附 1-(2-吡啶偶氮)2-萘酚 

分 类 号：O657.32[理学—分析化学]