由2-烷基蒽醌一步法制备2-烷基蒽(英文)  

A Facile One-step Synthesis of 2-Alkylanthracene from 2-Alkylanthraquinone

作　　者：赵春梅[1] 徐莉[2] 王华[1] 

机构地区：[1]河南大学教育部特种功能材料重点实验室,河南开封475004 [2]河南大学化学化工学院,河南开封475004

出　　处：《化学研究》2007年第4期13-15,19,共4页Chemical Research

基　　金：This research was supported by the National Science Foundation of China (20572015, 20672028);Program for NewCentury Ex-cellent Talents in University (NCET-05-0610);the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Min-istry (SRF for ROCS, SEM);Program for Young Excellent Talents in Henan Universities;Foundation of Education Department of Henan Province(2006150004);Program for Extraordinary Professors of Henan University and the Key Foundation of Henan University (04ZDZR013)

摘　　要：本文报道了以2-烷基蒽醌为原料,结晶硫酸铜为催化剂,锌粉为还原剂于浓氨水(25%～28%)中一步法制备2-烷基蒽.产物通过硅胶柱层析,收率范围:55%～90%.文中从取代基的电子效应和空间位阻角度分析了产率的变化规律.同时考察了其它几种无机盐用作催化剂的催化作用.One-step synthesis of 2-alkylanthracene from the corresponding 2-alkylanthraquinone in the presence of copper sulfate pentahydrate as a catalyst is presented in this paper. The reduction is earried out in a concentrated ammonia solution （25 % -28 % ） with zinc dust as reducer. The products are easy to be purified by column chromatography with yields of 55 % -90 %. The electric effect and sterie hindrance from alkyl groups controlling the yields were discussed. In addition, other inorganic salts acted as catalysts were investigated.

关 键 词：2-烷基蒽醌 2-烷基葸 结晶硫酸铜 锌粉 还原反应 

分 类 号：O625[理学—有机化学]