2,4,4-三甲基-2-氯戊烷与1,1一二苯基乙烯的正碳离子反应(Ⅰ)──反应的主要特点  

Carbocationic Reaction Between 2, 4, 4-Trimethy1-2-chloropentane and 1, 1-Diphenyl Ethylene(Ⅰ)──Main Features of the Reaction

作　　者：曹宪一[1] 周心如[1] 初广成 武冠英[1] 

机构地区：[1]北京化工大学高分子材料研究所,北京100029

出　　处：《高等学校化学学报》1997年第2期329-331,共3页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金;国家教育委员会留学回国人员基金

摘　　要：篢he carbocationic reaction between 2, 4, 4-trimethy1-2-chloropentane, which is a model compound of polyisobutylene’s end group, and 1, ldsdiphenyl ethylene was investigated by high pressure liquid chromatography, it was found that the reaction presents a strong reverse reaction even if at low temperature. The ceiling temperature is about -18℃. The reaction with tirne and effect of concentration of TiCl4, temperature, polarity of solvent on the reaction show that the main features of this reaction are very close to that of carbocationic polymerization of isobutylene. So the reaction would be ideal model reaction for the carbocationic polymerization.篢he carbocationic reaction between 2, 4, 4-trimethy1-2-chloropentane, which is a model compound of polyisobutylene's end group, and 1, ldsdiphenyl ethylene was investigated by high pressure liquid chromatography, it was found that the reaction presents a strong reverse reaction even if at low temperature. The ceiling temperature is about -18℃. The reaction with tirne and effect of concentration of TiCl4, temperature, polarity of solvent on the reaction show that the main features of this reaction are very close to that of carbocationic polymerization of isobutylene. So the reaction would be ideal model reaction for the carbocationic polymerization.

关 键 词：三甲基 正碳离子聚合 异丁烯 氯戊烷 二苯基乙烯 

分 类 号：O632.12[理学—高分子化学]