双核铜配合物的合成、结构和性质研究  

SYNTHESIS,STRUCTURE AND CHARACTERIZATION OF BINUCLEAR COPPER(Ⅱ) COMPLEXES

作　　者：杨瑞娜 薛宝玉 王冬梅 侯益民 金斗满 李彩云 

机构地区：[1]河南化学研究所 [2]平原大学

出　　处：《化学研究与应用》1997年第2期185-189,共5页Chemical Research and Application

基　　金：国家自然科学基金;南京配位化学重点实验室资助

摘　　要：双核铜配合物的合成、结构和性质研究＊杨瑞娜薛宝玉王冬梅侯益民金斗满（河南化学研究所，郑州４５０００３）李彩云（平原大学，新乡４５３００３）关键词铜双核配合物氧化加成中图分类号Ｏ６２７．１２众所周知，许多金属酶具有铜（Ⅰ）、铜（Ⅱ）活性中心，铜配合物具...At room temperature,the binuclear copper(Ⅱ) complexes [Cu(C 6H 5COO) 2(L)] 2,L=C 5H 5NO(1),2-methylpyridine(2),2,4,6-trimethylpyridine(3),[Cu 2(C 6H 5COO) 4(dppe)](4,deep=di(biph-enylphosphine) ethane were prepared by oxidative addition reaction.The complexes were characterized by elemental analyses,IR spectra,TG-DTA and magnetic properties.Crystals (1) are triclinic,space group P1,Z=1,V=0.880nm 3, R= 0.044, a=0.9262(4),b=1.0697(2),c =1.0881(3)nm,a=59.60(2)°,β=74.83(3)°,γ=72.80(2)°.Each copper(Ⅱ) ion is coordinated by four bridging bidentate benzoate and one ligand forms dimeric binuclear molecules.

关 键 词：铜 双核配合物 氧化加成 

分 类 号：O614.121[理学—无机化学]