气相色谱-质谱法分析芥子气的氯氨消毒产物  

Gas Chromatography-Mass Spectrometric Analysis of Detoxicated Products of Mustard by Chloramines

作　　者：周黎明[1] 顾惠芬[1] 曲刚莲[1] 钟玉征[1] 

机构地区：[1]防化指挥工程学院第八教研室,北京102205

出　　处：《分析化学》1997年第9期1068-1071,共4页Chinese Journal of Analytical Chemistry

摘　　要：用气相色谱／质谱法（ＧＣ／ＭＳ）分析了芥子气的氯胺Ｔ、氯胺Ｂ的消毒产物。根据消毒剂和消毒产物的性质，研究了不同消毒液样品制备方法。探讨了消毒剂过量和不过量时对消毒反应的影响。建立了消毒产物的ＧＣ／ＭＳ分析的条件。不仅跟踪了芥子气的消毒程度，而且检出了不同的消毒剂在不同的消毒条件下产生的消毒产物，并对各产物进行了定性鉴定。The detoxicated products of mustard with chloramine-T and chloramine-B were analyzed by gas chromatography-mass spectrometry(GC/MS). According to the property of detoxication agents and the detoxicated products, sample preparation methods were studied. The detoxication efficiency by use of stoichiometric or excess amount of detoxication agents. was probed. A GC-MS method for qualitative analysis of detoxicated products was estab- lished.

关 键 词：气相色谱 质谱法 芥子气 氯胺 消毒产物 

分 类 号：E929.1[军事—军事装备学]