3,4-Diphenylcycl[3,2,2]azine类化合物的合成及其光学性质研究  

Synthesis and Optical Properties of 3,4-Diphenylcycl[3,2,2]azines

作　　者：吴婧[1] 刘磊[1] 陈维[1] 韩巧荣[1] 王炳祥[1] 沈健[1] 

机构地区：[1]南京师范大学化学与环境科学学院江苏省生物医药功能材料工程研究中心,江苏南京210097

出　　处：《南京师大学报（自然科学版）》2007年第4期53-55,共3页Journal of Nanjing Normal University(Natural Science Edition)

基　　金：江苏省教育厅自然科学基金(04KJD150103);南京师范大学青蓝工程奖励基金资助项目.

摘　　要：合成了3个不同取代基的3,4-Diphenylcycl[3,2,2]azine类化合物,首次测试了它们各自的紫外光谱和荧光光谱,计算了它们的荧光量子效率和Stoke’s位移,对比讨论了取代基效应对其紫外光谱和荧光光谱的影响,发现了其分子结构与光谱性质之间的某些规律性的关系.Three 3,4-Diphenylcycl [3,2,2 ] azines were synthesized and their UV/Vis and fluorescence spectra were measured. Their fluorescence quantum yields and Stoke＇ s shifts were determined, and the substituent effect on their UV/Vis and fluorescence spectra was studied. Some of the relationships between chemical structure and the corresponding optical properties were found.

关 键 词：Cycl[3 2 2]azine 紫外光谱 荧光光谱 取代基效应 

分 类 号：O626[理学—有机化学]