ZnMgAl复合氧化物催化合成丙二醇苯醚  

ZnMgAl mixed oxides derived from hydrotalcite-like compounds for synthesis of propane diol phenyl ether

作　　者：程文萍[1] 王雯娟[1] 赵月昌[1] 刘玲[1] 邵丽丽[1] 杨建国[1] 

机构地区：[1]华东师范大学化学系上海市绿色化学与化工过程绿色化重点实验室,上海200062

出　　处：《化工学报》2007年第12期3072-3076,共5页CIESC Journal

基　　金：上海科学技术发展基金项目(03DJ14005)~~

摘　　要：以不同类水滑石化合物为前驱体制得的复合氧化物作为合成丙二醇苯醚反应的固体碱催化剂,考察了催化剂组成、结构及反应条件对催化合成丙二醇苯醚反应的影响。结果发现,在所制备的固体碱催化剂中ZnMgAl复合氧化物显示出高效的催化活性和选择性,在催化剂用量为1.1%,C6H5OH/PO摩尔比为1∶1,反应温度为413K和反应时间为5h的条件下,环氧丙烷的转化率达到97.2%,丙二醇苯醚的选择性达93.4%。Propanediol phenyl ether was synthesized from phenol and propylene oxide（PO）in the presence of a series of solid-based catalysts derived from hydrotalcite-like compounds.The effects of the composition and structure of the catalysts,and the reaction conditions on the synthesis of propanediol phenyl ether were studied.The optimum reaction conditions were as follows：the amount of ZnMgAl catalyst was 1.1%,the molar ratio of C6H5OH to PO was 1∶1,reaction temperature was 413 K,and reaction time was 5 h.The conversion of PO was 97.2%,the selectivity of propanediol phenyl ether was 93.4%.

关 键 词：固体碱催化剂 环氧丙烷 苯酚 丙二醇苯醚 

分 类 号：TQ203.2[化学工程—有机化工]