新型无卤阻燃剂六苯胺基环三磷腈的合成  

Synthesis of new type non- halogen fire retardancy hexa(aniline)cyclotriphosphazene

作　　者：孙德[1] 高维全[2] 李然[1] 张龙[1] 唐淑娟[2] 

机构地区：[1]长春工业大学化学工程学院,吉林长春130012 [2]长春工业大学艺术设计学院,吉林长春130012

出　　处：《中国氯碱》2007年第12期9-10,42,共3页China Chlor-Alkali

摘　　要：由五氯化磷和氯化铵合成了六氯环三磷腈(Ⅰ),通过亲和取代反应由苯胺和Ⅰ合成了六(苯胺基)环三磷腈(Ⅱ),对反应条件进行了优化,并对化合物Ⅰ、Ⅱ进行了元素分析、IR谱和质谱表征。用化合物Ⅱ与ABS树脂共混制备了阻燃ABS树脂,测试了其氧指数和力学性能等指标。Hexaehloroeyelotriphosphazene （ Ⅰ ） was synthesized with pentaehloide and ammonium chloride, and the hexa （aniline）eyelotriphosphazene （ Ⅱ） were synthesized by Ⅰ reacting with aniline through nueleophilie substitution. Reaction stations were optimized, including solvent, reaction time and temperature. Compound Ⅰ ,Ⅱ was characterized by MS speetra,IR spectra,elementary composition. Fire-resistant ABS resin were prepared by compound Ⅱ and ABS resin, and the limited oxygen index （LOI） and other mechanical properties were tested.

关 键 词：六氯环三磷腈 六(苯胺基)环三磷腈 表征 阻燃ABS树脂 

分 类 号：TQ314.248[化学工程—高聚物工业] TQ265.1