多氨基多醚基亚甲基膦酸盐的合成与阻垢性能  

Synthesis of polyamine polyether methylene phosphonates and its scale inhibition property

作　　者：吕翔[1] 雷武[2] 夏明珠[2] 王风云[2] 

机构地区：[1]南京中医药大学药学院,江苏南京210046 [2]南京理工大学工业化学研究所,江苏南京210094

出　　处：《工业水处理》2007年第12期43-46,共4页Industrial Water Treatment

摘　　要：以端氨基聚醚、亚磷酸和甲醛等为原料合成了多氨基多醚基亚甲基膦酸盐(PAPEMP)。系统地研究了反应温度、反应时间、甲醛和端氨基聚醚的物质的量比等因素对目标产物PAPEMP阻垢性能的影响,由此得到PA-PEMP的最佳合成工艺条件为:反应温度105℃、反应时间3.5 h、n(甲醛)n∶(端氨基聚醚)=51∶。此外,还初步研究了铁离子对合成反应的影响。Polyamine polyether methylene phosphonates（PAPEMP） has been synthesized by using polyoxypropylenediamine,phosphorous acid,concentrated hydroehlorie aeid and formaldehyde. The effeet of different synthesis eonditions on the seale inhibition property of the produet has been studied. The optimal reaetion eonditions are ： the reaetion temperature is 105 ℃, the reaetion time 3.5 h, the mole ratio of formaldehyde to polyoxypropylene- diarnine is 5 ： 1 o The seale inhibition effieieney of this produet is high. The effeet of iron irons on synthetie reaetion is studied.

关 键 词：多氨基多醚基亚甲基膦酸 阻垢性能 循环冷却水 

分 类 号：TQ085.4[化学工程] O621[理学—有机化学]