多孔金属-有机络合聚合物结构特征与其吸附行为关系  

Correlation between Structural Characteristics and Adsorption Behaviors of Porous Metal-Organic Coordination Polymers

作　　者：胡传彬[1] 杨明莉[2] 鲜学福[2] 幸良淑[1] 张新涛[1] 

机构地区：[1]重庆大学化学化工学院,重庆400044 [2]西南资源开发及环境灾害控制教育部重点实验室,重庆400044

出　　处：《材料导报》2008年第1期45-48,57,共5页Materials Reports

基　　金：重庆市院士基金(CSTC-2005AB6007)

摘　　要：综述了近来出现的一类有前途的多孔材料——金属-有机络合聚合物(MOCPs)吸附功能的设计策略与合成途径。通过配体结构的选择或修饰可赋予MOCPs特定吸附性的孔环境;或采用适当的设计和合成策略使过渡金属离子和有机配体形成的骨架结构对特定吸附质分子具有特定的选择性。为新型的多孔吸附剂的设计与制备提供了一种新思路。In the paper the approaches to design and synthesis of a new class of promising porous absorbentsmetal-organic coordination polymers （MOCPs）are reviewed. It is possible to obtain porous microenvironment with specific inner surfaces by selecting proper ligands or by ligands modified with specific functional groups and to prepare the MOCPs with a selectivity to some kind of target molecules by taking suitable strategies of design and synthesis. All of these provide us with a fire-new clue to new type porous sorbent design.

关 键 词：金属-有机络合聚合物 金属有机骨架 孔结构 比表面积 气体吸附 

分 类 号：TS106.8[轻工技术与工程—纺织工程]