卟啉低聚物的合成与表征  

Synthesis and characterization of porphyrin low-polymer

作　　者：付瑶[1] 石莹岩[1] 吴晓燕[2] 

机构地区：[1]吉林建筑工程学院基础科学部,吉林长春130021 [2]东北师范大学化学学院,吉林长春130024

出　　处：《东北师大学报（自然科学版）》2007年第4期94-96,共3页Journal of Northeast Normal University(Natural Science Edition)

基　　金：吉林省科技发展计划项目(20060571)

摘　　要：以单体5-(4-羟基苯基)-10,15,20-三苯基卟啉(H2MHTPP)与5,15-二(4-羟基苯基)-10,20-二苯基卟啉(trans-H2DHDPP)做单体,1,3-二溴丙烷做桥连剂,合成了一种一维纳米卟啉低聚物.通过元素分析、紫外光谱、红外光谱1、H核磁共振等手段对其结构进行了表征,确证了其结构.A one-dimension nano-porphyrin oligomer is synthesized.Monomer 5-（4-hydroxyl phenyl）-10,15,20-3-phenyl porphyrin and 5,15-2（4-hydroxyl phenyl）-10,20-2-phenyl-porphyrin as monomer 1,3-2-bromine propane as bridge connecting material to compose the nano-porphyrin oligomer are employed.The construction of porphyrin oligomer is featured and confirmed by the element analysis,ultraviolet spectrum,infrared spectrum and 1 H NMR.

关 键 词：卟啉低聚物 合成 表征 

分 类 号：O62[理学—有机化学]