N-硝基-2,6-二硝基-4-三氟甲基苯胺类化合物的合成及其活性  

Synthesis of N-Nitro-2,6-dinitro-4-trifluoromethylanilines and Their Plant Regulating Activities

作　　者：江洪[1] 方利[1] 崔燕[1] 陈长水[1] 

机构地区：[1]华中农业大学化学系,武汉430070

出　　处：《农药》2008年第1期26-28,共3页Agrochemicals

基　　金：国家自然科学基金项目(No.39770845);华中农业大学博士基金(No.52204-05047)

摘　　要：3,5-二硝基-4-氯三氟甲苯与胺反应生成2,6-二硝基-4-三氟甲基苯胺,以乙酰硝酸酯作硝化剂,代替直接以发烟硝酸作硝化剂,浓硫酸作溶剂,合成N-硝基-2,6-二硝基-4-三氟甲基苯胺。产物结构经IR、1HNMR、质谱、元素分析表征。生测结果表明目标产物对水稻和油菜有一定的生长调节作用。3,5-Dinitro-4-chlorotrifluoromethane reacted with amines produced 2,6-dinitro-4-trifluoromethylanilines. N-Nitro-2,6-dinitro-4-trifluoromethylanilines were prepared by nitration of 2,6-dinitro-4-trifluoromethylaniline in concentrated sulfuric acid with acetyl nitrate instead of directly using nitric acid as nitrating agent. Their structures were confirmed by IR,^1H NMR, MS spectra and elemental analyses, The biological test results showed that the target compounds have some regulating effects on rice and rape,

关 键 词：N-硝基取代苯胺 硝化 调节作用 

分 类 号：TQ450.2[化学工程—农药化工]