球磨改性处理对Ti9．6Cr11V75．4Fe4合金储氢性能的影响  

Influence of Ball-Milling on Hydrogen Storage Properties of Ti_(9.6)V_(75.4)Cr_(11)Fe_4 Alloy

作　　者：杭州明[1] 郑坊平[2] 王春涛[3] 范修林[1] 李寿权[1] 陈长聘[1] 陈立新[1] 

机构地区：[1]浙江大学材料科学与工程学系,杭州310027 [2]西安热工研究院材料部,西安710032 [3]浙江海洋学院机电工程学院,舟山316004

出　　处：《西安交通大学学报》2008年第1期114-118,共5页Journal of Xi'an Jiaotong University

基　　金：国家高技术研究发展计划资助项目(2006AA05Z144);国家自然科学基金资助项目(50571089);浙江省重大科技专项资助项目(2006C11233)

摘　　要：系统研究了机械球磨改性处理时间(t=0,1,2,4,8 h)对Ti9.6Cr11V75.4Fe4合金相结构和储氢性能的影响.XRD及扫描电镜分析表明,Ti9.6Cr11V75.4Fe4合金在球磨前后均为体心立方结构的固溶体单相,随着球磨时间的增加,合金的晶胞体积略微减小,合金颗粒逐渐细化并发生团聚.储氢性能测试表明,球磨改性处理能有效地改善合金的活化性能,随着球磨时间的增加,合金的室温可逆有效储氢量先增加后降低.其中,当球磨时间为2 h时,合金具有最佳的综合储氢性能,其室温最大吸氢量(质量分数)为3.7%,可逆有效储氢量(质量分数)为2.23%.The changes in phase structure and hydrogen storage properties of Ti9.6 Cr11 V75.4 Fe4 alloy after modification by ball-milling for different time （t=0, 1, 2, 4, 8 h） are systematically in- vestigated. The XRD and SEM analyses show that all of the as-cast and ball-milled alloys consist of a single V-based solid solution phase with BCC structure. The cell volume and the particle size decrease gradually and the powder appears aggregation with the increasing ball-milling time. It is found that the ball-milling enables to improve the activation behavior of Tig.6Cr11 V75.4 Fe4 alloy effectively. With the increasing ball-milling time, the effective hydrogen storage capacity at room temperature increases first and then decreases. Tig.6Crn V75.4Fe4 alloy ball-milled for 2 h is endowed with fine overall properties, whose maximum hydrogen absorption capacity and effective hydrogen storage capacity at room temperature approach to 3.7% and 2.23%, respectively.

关 键 词：Ti—Cr—V—Fe系合金 球磨改性 钒基固溶体 储氢性能 

分 类 号：TG139.7[一般工业技术—材料科学与工程]