8-羟基喹啉铋的合成、表征与光谱研究  

Synthesis,characterization and spectra of the solid complex of bismuth with 8-hydroxyquinoline

作　　者：蒋琪英[1] 陈明剑[1] 胡亚敏[1] 沈娟[1] 钟国清[1] 

机构地区：[1]西南科技大学材料学院化学系,四川绵阳621010

出　　处：《化学研究与应用》2008年第1期58-61,共4页Chemical Research and Application

基　　金：四川省科技厅资助项目(05JY029-113);西南科技大学人才基金;青年基金项目(ZK043129;ZK053012)

摘　　要：A new solid bismuth complex,[C9H8ON]3·2H2O,was synthesized by bismuth trichloride and 8-hydroxyquinoline(8-Hhq) in dilute HCl.The complex was characterized by elemental analysis,XRD,TG-DSC and FT-IR.The IR result shows that the heterocyclic nitrogen atom of 8Hhq bonds to H+,and coordinates with Bi3+.The fluorescent spectra and UV-Vis spectra of the title compound were carried out.A new solid bismuth complex, [ C9HsON]3 [ BiCI6 ] · 2H2O, was synthesized by bismuth trichloride and 8- hydroxyquinoline （8-Hhq） in dilute HCL, The complex was characterized by elemental analysis, XRD, TG-DSC and FF-IR. The IR result shows that the heterocyclic nitrogen atom of 8Hhq bonds to H^＋ , and coordinates with Bi^3＋, The fluorescent spectra and UV-Vis spectra of the title compound were carried out.

关 键 词：铋配合物 8-羟基喹啉 结构 表征 光谱性质 

分 类 号：O614.53[理学—无机化学] O641.4[理学—化学]