含联吡啶或邻菲绕啉过渡金属配正离子与[Ni(cdc)_2]^(2-)的加合物的合成和波谱性质  

SYNTHESIS AND SPECTROSCOPIC PROPERTIES OF ADDUCTS OF TRANSITION-METAL COMPLEX CATIONS CONTAINING 2, 2'-BIPYRIDINE OR 1, 10-PHENANTHROLINE LIGANDS WITH [Ni(cdc)_2]^(2-)

作　　者：谢斌[1] 李金山[2] 

机构地区：[1]四川轻化工学院基础部,自贡643033 [2]南开大学元素有机化学研究所,天津300071

出　　处：《南开大学学报（自然科学版）》1997年第3期14-14,共1页Acta Scientiarum Naturalium Universitatis Nankaiensis

基　　金：国家自然科学基金

摘　　要：合成了一系列含联吡啶或邻菲绕啉配体过渡金属配正离子与双（N-氰基亚胶基二硫代甲酸）合镍负离子的加合物，其通式为［ML2］［Ni（Cdc）2］（M＝Cu，Ni，CO；L＝bpy，Phen），［L2Cu2（P－C2O4）］［Ni（cdc）2］（L＝bpy，Phen）以及［M（Phen）n］［Ni（cdc）2］·2H2O（n＝1，M＝Cu；n＝2，M＝Zn）．通过元素分析、红外光谱、电子光谱、磁化率和顺磁共振谱对这些加合物进行了表征，讨论了正、负离子间的相互作用．A series of adducts of transition-metal complex cations containing 2, 2'-bipyridine or1,10-phenanthroline ligands with bis (N-cyanodithiocarbimato)nickelat anion, which havethe general formula [ML2] [Ni (cdc )2] (M = Cu, Ni, Co; L = bpy, phen ), [L2Cu2 (μ - C2O4 )][Ni(cdc)2] (L=bpy,phen) and [ M (phen)n][Ni (cdc)2]· 2H2O(n = 1,M=Cu； n = 2,M=Zn),have been synthesized. These adducts have been characterized by elemental analy-sis, infra-red spectra, electronic spectra, electron paramagnetic resonance spectra andmagnetic susceptibility. The interaction between cations and anion was discussed.

关 键 词：过渡金属 加合物 邻菲绕啉 邻菲绕啉 配合物 

分 类 号：O641.4[理学—物理化学]