苯胺对间歇及连续运行硝化过程的毒性抑制试验  

Inhibition Investigation of Aniline on Nitrification Process in Batch and Continuous Running Reactors

作　　者：吴锦华[1] 韦朝海[1] 李平[1] 

机构地区：[1]华南理工大学环境科学与工程学院,广州510640

出　　处：《环境科学》2008年第1期109-113,共5页Environmental Science

基　　金：国家自然科学基金项目(50278036);广东省自然科学基金项目(04105951;05300188);华南理工大学基金项目

摘　　要：以经过驯化的苯胺降解菌和硝化菌作为菌源,在悬浮污泥间歇反应器中及三相流化床反应器中分别考察了间歇及连续进水2种工艺条件下苯胺对硝化过程的毒性抑制作用.结果表明,苯胺对悬浮污泥间歇反应器中的硝化菌有较强的抑制作用,仅当苯胺浓度低于3 mg/L时,硝化菌的活性才能逐渐恢复,且恢复的时间随着苯胺的初始浓度的增高而延长.实验结果还显示,适宜的水力停留时间(HRT)是保证三相流化床中苯胺成功降解及硝化脱氮的关键工艺条件.当进水苯胺浓度为200 mg/L,HRT为10 h时,反应液中苯胺浓度为6.58 mg/L,硝化率可达84.95%,由此表明膜硝化反应器抵抗苯胺毒性抑制的能力强于悬浮污泥硝化反应器,在工业上采用三相流化床膜硝化反应器对含毒性有机物的废水进行硝化脱氮处理是有实际应用价值的.Inhibition effect of aniline on nitrifier was investigated in suspended sludge batch reactors and a three-phase fluidized bed, The tested nitrifier and aniline degradation bacteria were obtained from excess sludge of a treatment plant for aniline wastewater. The results showed that aniline had produced obvious inhibition on nitrifier in suspended sludge batch reactors. Barely when aniline concentration was less than 3 mg/L, had nitrifier gradually recovered their ability. But the recovered time prolonged with the augment of initial aniline concentration. Feasible hydraulic retention time （HRT） was a key operating factor to remove aniline and ammonia simultaneously in fluidized bed reactor. When aniline concentration in influent was 200 mg/L and HRT was 10 h, aniline concentration was 6.58 mg/L and nitrifying rate achieved 84.95 % in the fluidized bed reactor. Three-phase fluidized biofilm nitrifying reactor was superior to suspended sludge nitrifying reactor in resisting aniline toxicity and has practical value in denitrifying treatment of wastewater containing toxic organic chemicals.

关 键 词：苯胺废水 硝化 抑制作用 三相流化床 

分 类 号：X703.1[环境科学与工程—环境工程]