秸秆燃气合成甲醇的热力学试验研究  

Experimental Study on the Thermodynamics of Methanol Synthesis from Cornstalk Gases

作　　者：朱灵峰[1] 杜磊[1] 王永豪[1] 何卫卫[1] 陈志冉[1] 张百良[2] 

机构地区：[1]华北水利水电学院,河南郑州450011 [2]河南农业大学,河南郑州450002

出　　处：《河南农业大学学报》2007年第6期707-710,共4页Journal of Henan Agricultural University

基　　金：河南省教育厅科技攻关项目(2007610008)

摘　　要：采用热化学方法,将玉米秸秆裂解为生物质燃气,并对该燃气进行优化试验,制备出合成气.在直流流动等温积分反应器中,采用国产C 301铜基催化剂,对玉米秸秆合成气催化合成甲醇进行了试验.运用SHBWR状态方程,计算了加压下秸秆合成气合成甲醇反应体系的密度及状态方程参数.In order to investigate the conversion of cornstalk biomass into the industrial product（synthesis of fuel methanol） and the effective utilization of biomass energy,the pyrolysis test of cornstalk biomass fuel gas was carried out by means of the thermochemical method.With the optimum test result,the cornstalk synthesis gas was prepared.The catalytic synthesis of methanol from the cornstalk syngas using the catalyst,domestic Cu-based C301 was carried out in a tubular-flow integral and isothermal reactor.Through the SHBWR state equation,the equation parameters and the density data were calculated under high pressure for the systems studied.

关 键 词：生物质 催化 甲醇 合成 秸秆 

分 类 号：TK6[动力工程及工程热物理—生物能] TQ013.1[化学工程]