激光诱导吡咯和邻苯二胺的电化学聚合  

Laser induced Electropolymerization of Pyrrole and o Phenylenediamine for Micro patterns Fabrication

作　　者：高劲松[1] 蔡雄伟[1] 田中群 

机构地区：[1]厦门大学固体表面物理化学国家重点实验室

出　　处：《应用化学》1997年第2期72-74,共3页Chinese Journal of Applied Chemistry

基　　金：国家自然科学基金

摘　　要：激光诱导吡咯和邻苯二胺的电化学聚合高劲松蔡雄伟田中群＊（厦门大学固体表面物理化学国家重点实验室，化学系，物理化学研究所厦门３６１００５）关键词激光诱导，电化学聚合，微加工，聚吡咯，聚邻苯二胺１９９６－０８－１２收稿，１９９６－１１－１８修回国家自然科...It has been shown that laser can induce selective local electropolymerization of polypyrrole (PPY) and poly o phenylenediamine(POPD). The resonance Raman spectroscopic result indicates that the structure of the laser induced PPY is nearly identical to that of the PPY formed under the normal condition of electropolymerization. It seems to be reasonable to assume that the laser induced thermal effect is most likely to influence the electropolymerization kinetics, as the temperature rise at the illuminated surface area results in considerable shift of the equilibrium potential. Electrochemical micro patterns were achieved by laser induced electropolymerization of PPY and POPD on Au and HOPG electrode. The diameter of points and the width of lines obtained are about 2￣4 and 8 micrometers respectively.

关 键 词：激光诱导 电化学聚合 聚吡咯 聚邻苯二胺 

分 类 号：O633[理学—高分子化学]