O-(1,2,2,2-四氯乙基)硫逐磷酰二氯及其对应的磷酰一氯的合成研究  

Preparation of O (1,2,2,2 Tetrachloroethyl)phosphorothioic Dichloride and Its Phosphorothioic Chloride

作　　者：何良年[1] 蔡飞[1] 张景龄[1] 

机构地区：[1]华中师范大学有机合成所

出　　处：《精细化工》1997年第4期60-62,共3页Fine Chemicals

摘　　要：采用硫化氢作为硫化试剂以五氯化磷作为原料合成Ｏ－（１，２，２，２－四氯乙基）硫逐磷酰二氯（２）及其对应的磷酰一氯化物（３）。通过使用催化剂Ｈｃ，使得制备（２）的收率提高到７０％。初步的生测实验结果表明（２）和（３）具有较好的杀虫活性。O (1,2,2,2 Tetrachloroethyl)phosphorothioic dichloride (2) and its phosphorothioic chloride (3) were prepared using hydrogen sulfide as a sulfurizing agent from phosphorus pentachloride and chloral.The yield of compound (2) is about 70% in the presence of catalyst Hc.The results of the preliminary bioassay indicate compound (2) and (3) have good insecticidal activities.

关 键 词：硫逐磷酰氯 试剂 农药 杀虫剂 磷酰一氯 有机磷 

分 类 号：TQ453.22[化学工程—农药化工]