高度有序介孔氧化硅材料SBA-15：高浓度氨基官能化及氨基及氨基团的可利用性(英文)  

Highly Ordered Mesoporous Silica SBA-15 Functionalized with High Concentration of Amino Groups Accessible to Metal Ions

作　　者：韦奇[1] 钟振兴[1] 聂祚仁[1] 陈慧巧[1] 李群艳[1] 李从举[2] 

机构地区：[1]北京工业大学材料科学与工程学院,北京100022 [2]北京服装学院北京市服装材料研发与评价重点实验室,北京100029

出　　处：《无机化学学报》2008年第1期130-137,共8页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.50525413,50502002,50503001);北京市教委科技计划(No.KM200610005016)资助项目

摘　　要：采用简单的方法合成高浓度氨基修饰的高度有序氧化硅材料并深入研究氨基官能化材料的孔结构以及氨基的存在状态和可利用性。结果表明,氨基基团共价连接到SBA-15的孔表面,即使初始合成体系中的APTES(氨丙基三乙氧基硅烷)浓度高达30mol%时材料依然保持高度的有序性。合成体系中APTES浓度为20%的样品还保持良好的介孔结构,比表面积为680m2.g-1,孔容为0.89cm3.g-1,此介孔结构中的氨基官能团对镍离子表现出很强的亲和力,Ni2+的吸附量高达1.88mmol.g-1,相比之下未官能化的SBA-15对Ni2+没有吸附作用。当初始合成体系中APTES的浓度进一步增大到30%时,修饰到介孔氧化硅材料的氨基含量也随之增大,但由于材料的孔隙度急剧降低,这些氨基的可利用性也降低。A facile strategy was used to synthesize highly ordered mesoporous silica SBA-15 functionalized with high concentration of amino groups,which seems to be rather difficult to be incorporated into mesoporous silica without disrupting the ordered mesoscopic structure compared to other functional groups.The pore structure of functionalized materials,together with the presence and accessibility of functional groups,were investigated in detail.It is shown that amino groups are attached covalently to the pore wall of SBA-15 and the ordered mesoscopic architecture of the functionalized samples remains almost intact even with a large concentration of aminopropyltriethoxysilane（APTES）up to 30mol% in the initial synthetic mixture.The samples with 20mol% APTES in the initial reaction mixture still preserve a desirable pore structure,with a surface area of 680 m^2·g^-1 and a pore volume of 0.89 cm^3·g^-1.Furthermore,the functional groups in such a porous structure are readily accessible and show a large affinity for nickelⅡ ion,with a Ni^2＋ adsorption capacity of 1.88 mmol·g^-1,whereas no Ni^2＋ adsorption takes place with unfunctionalized mesoporous silica.The amount of amino groups incorporated increase as the APTES concentration further increases to 30mol%,but the amino groups are less accessible due to the dramatic decrease in the porosity of functionalized samples.

关 键 词：氨基 介观有序度 孔结构 金属离子吸附 

分 类 号：O612.4[理学—无机化学] O623.732[理学—化学]