一种铀(Ⅵ)配合物的水热合成、结构与性质(英文)  

Hydrothermal Synthesis,Structure and Fluorescent Property of a Coordination Compound of Uranyl(Ⅵ)

作　　者：金杨波[1] 胡斌[1] 李永绣[1] 王国喜[2] 

机构地区：[1]南昌大学稀土与微纳功能材料研究中心,南昌大学高等研究院,南昌330047 [2]安阳工学院化学与环境工程系,安阳455000

出　　处：《无机化学学报》2008年第1期138-140,共3页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金(No.201610002);江西省自然科学基金(No.0220007);江西省教育厅基金资助项目

摘　　要：UO2(EPC)2(EPC=5-ethyl-3-pyridinecarboxylate)was synthesized by the hydrothermal reaction of UO2(NO3)2 ·6H2O with imazethapyr [2-(4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl)-5-ethyl-3-pyridine-carboxylic acid] at 120 ℃,which 2-(4,5-dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl group was removed under this condition to result in the formation of 5-ethyl-3-pyridinecarboxylate ligand(EPC).The structure and fluorescent property of the synthesized complex is also reported.CCDC:645641.UO2（EPC）2（EPC=5-ethyl-3-pyridinecarboxylate）was synthesized by the hydrothermal reaction of UO2（NO3）2 ·6H2O with imazethapyr [2-（4,5-dihydro-4-methyl-4-（1-methylethyl）-5-oxo-1H-imidazol-2-yl）-5-ethyl-3-pyridine-carboxylic acid] at 120 ℃,which 2-（4,5-dihydro-4-methyl-4-（1-methylethyl）-5-oxo-1H-imidazol-2-yl group was removed under this condition to result in the formation of 5-ethyl-3-pyridinecarboxylate ligand（EPC）.The structure and fluorescent property of the synthesized complex is also reported.CCDC：645641.

关 键 词：铀酰配合物 水热合成 晶体结构 荧光 

分 类 号：O614.62[理学—无机化学]