Ketalization of Catechol with Carbonyl Compounds Catalyzed by Metal p-Toluenesulfonate as Biphasic Acid Catalyst  被引量:1

Ketalization of Catechol with Carbonyl Compounds Catalyzed by Metal p-Toluenesulfonate as Biphasic Acid Catalyst

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作  者:梁学正 高珊 王雯娟 程文萍 杨建国 

机构地区:[1]Shanghai Key Laboratory of Green Chemistry and Chemical Process, East China Normal University, Shanghai 200062, China

出  处:《Chinese Journal of Chemical Engineering》2008年第1期124-127,共4页中国化学工程学报(英文版)

基  金:National Key Project of Scientific and Technical Supporting Programs Funded by Ministry of Science & Tech- nology of China (No.2006BAE03B06)

摘  要:Ketalization of catechol was studied with various carbonyl compounds using metal p-toluenesulfonate as biphasic catalysts. The results showed that copper p-toluenesulfonate was the most efficient catalysts for the reaction. The advantages of high activity, stability, reusability and low cost for the simple synthetic procedure made the catalyst one of the best choice for the reaction.儿茶酚的 Ketalization 作为双性人用金属 p-toluenesulfonate 与各种各样的羰基化物被学习局面的催化剂。结果证明铜 p-toluenesulfonate 是为反应的最有效的催化剂。为简单合成过程的高活动,稳定性,可重用性和低费用的优点为反应使催化剂成为了最好的选择之一。

关 键 词:synthesis 1 3-benzodioxole biphasic acid catalyst metalp-toluenesulfonate 

分 类 号:O643.3[理学—物理化学]

 

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