聚丙烯混杂复合体系的界面和力学性能  

INTERFACE AND PERFORMANCE FOR POLYPROPYLENE HYBRID COMPOSITES

作　　者：欧玉春[1] 方晓萍[1] 冯宇鹏[1] 

机构地区：[1]中国科学院化学研究所工程塑料国家重点实验室

出　　处：《高分子学报》1997年第1期31-37,共7页Acta Polymerica Sinica

基　　金：国家自然科学基金

摘　　要：从刚性粒子增韧聚合物体系的界面层性质入手，研究了带有柔性分子链界面改性剂包覆的高岭土（Ｋａｏｌｉｎ）刚性粒子增韧的，短切玻纤（ＧＦ）增强的聚丙烯（ＰＰ）混杂复合体系的微观结构，结晶性质，ＰＰ／Ｋａｏｌｉｎ／ＧＦ混杂复合材料的加工流动性及力学性能．实验结果表明，所合成的界面改性剂对ＰＰ／Ｋａｏｌｉｎ复合材料有显著的增韧效果；加入少量的短切玻纤可以弥补因界面改性剂引入而引起的ＰＰ／Ｋａｏｌｉｎ复合材料强度和模量降低的缺点；经界面改性剂包覆的高岭土刚性粒子和短切玻纤同时加入ＰＰ，混杂复合后，ＰＰ复合材料的冲击韧性大幅度提高，材料的强度和模量不降低．这个结果不仅在较低的Ｋａｏｌｉｎ含量下。Based on interfacial layer properties of rigid particle toughening polymer system,microstructure,crystallization,processing flow behavior and mechanical properties of polypropylene(PP)hybrid composites,which were mixed with Kaolin coated by modifier with flexible molecular chain as a toughening agent and short glass fiber(GF) as a reinforcer,were studied by means of scanning electron microscopy(SEM),differential scanning calorameter(DSC),molten index test( MI ) and mechanical tests.The results shown that notched Izod impact strength( S I) of the PP composites is improved by hybrid modification,especially in the presence of 50%(wt%) Kaolin content,while tensile strength and flexible modulus of these composites are not decreased.

关 键 词：聚丙烯 聚合物混杂改性 界面改性剂 

分 类 号：TQ325.14[化学工程—合成树脂塑料工业]