CuO/CeO_2和CuO/Al_2O_3催化剂的催化性能  

Catalytic Properties of CuO/CeO 2 and CuO/Al 2O 3 Catalysts

作　　者：钟依均[1,2] 陈平[1,2] 周碧 罗孟飞[1,2] 

机构地区：[1]浙江师范大学化学系 [2]杭州大学催化研究所

出　　处：《应用化学》1997年第1期49-52,共4页Chinese Journal of Applied Chemistry

基　　金：浙江省应用化学重点实验室资助

摘　　要：本文以ＣＯ氧化为模式反应考察了ＣｅＯ２和Ａｌ２Ｏ３负载氧化铜催化剂的氧化活性，运用ＸＲＤ和ＴＰＲ技术研究了催化剂的还原性能和物相结构，结果表明：载体性质对负载ＣｕＯ催化剂的ＣＯ氧化活性有很大影响，ＣｕＯ／ＣｅＯ２催化剂活性明显高于ＣｕＯ／Ａｌ２Ｏ３催化剂．催化剂的还原特性随载体不同而不同．同时发现，热处理对催化剂铜物种的存在形式，晶粒大小、还原特性及其催化活性有明显影响，ＣｕＯ／Ａｌ２Ｏ３催化剂活性下降的主要因素是生成了活性较低的ＣｕＡｌ２Ｏ４相，而ＣｕＯ／ＣｅＯ２催化剂活性下降是由于ＣｕＯ和ＣｅＯ２发生烧结。The oxidation activity of CuO supported on CeO 2 and Al 2O 3 was investigated using the oxidation of carbon monoxide as a model reaction. The reducibility and Cu oxide species of the catalysts were studied by XRD and TPR techniques. The susceptibility of CO to oxidation strongly depends on the support: the catalytic activity of CuO/CeO 2 is much higher than that of CuO/Al 2O 3. It is found that the existing forms of copper species, crystal particle size of CuO, the reducibility and activity of catalysts are affected by thermal treatment. The formation of CuAl 2O 4 spinal species at high temperature is the main reason for activity decrease of CuO/Al 2O 3 catalyst, and the increase of crystal particle size of CuO is the main reason for activity decrease of CuO/CeO 2.

关 键 词：催化剂 还原特性 氧化活性 催化性能 氧化铜 

分 类 号：O643.36[理学—物理化学]