Synthesis of novel biscalixarene-tube containing two kinds of calix[4]arene derivative units  

作　　者：Fa Fu Yang Li M ing Liu Chao Hui Liu Xi-ao Hua Zheng Yu Guo 

机构地区：[1]College of Chemistry and Materials, Fujian Normal University, Fuzhou 350007, China

出　　处：《Chinese Chemical Letters》2008年第1期9-11,共3页中国化学快报（英文版）

基　　金：Financial support from the National Natural Science Foundation of China （No. 20402002）；Fujian Natural Science Foundation of China （No. 2006J0155）；Program for New Century Excellent Talents in University of Fujian Province were greatly acknowledged.

摘　　要：A novel biscalixarene with two kinds of calix[4]arene derivative units connected by four bridging chains, was facilely＇ synthesized by ＂1 ＋ 1＂ condensation mode in high yield. The element analyses, ESI-MS, ^1H NMR and ^1H-^1H COSY spectrum showed that the calix[4]arene units of compound 4 were in cone conformations and compound 4 possessed biscalixarene-tube structure. 2007 Fa Fu Yang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.A novel biscalixarene with two kinds of calix[4]arene derivative units connected by four bridging chains, was facilely＇ synthesized by ＂1 ＋ 1＂ condensation mode in high yield. The element analyses, ESI-MS, ^1H NMR and ^1H-^1H COSY spectrum showed that the calix[4]arene units of compound 4 were in cone conformations and compound 4 possessed biscalixarene-tube structure. 2007 Fa Fu Yang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

关 键 词：Biscalixarene TUBE SYNTHESIS ^1H-^1H COSY 

分 类 号：O625[理学—有机化学]