Sensitive determination of fenpropathrin,cyhalothrin and deltamethrin in environmental water samples using multiwalled carbon nanotubes cartridge prior to HPLC  

作　　者：Qing Xiang Zhou Guo Hong Xie Jun Ping Xiao Wei Dong Wang Yu Jie Ding 

机构地区：[1]School of Chemistry and Environmental Sciences, Henan Normal University, Henan Key Laboratory for Environmental Pollution Control, Key Laboratory for Yellow River and Huaihe River Water Environment and Pollution Control, Ministry of Education, Xinxiang 453007, China [2]College of Resources and Environment, Henan Institute of Science and Technology, Xinxiang 453003, China [3]Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China

出　　处：《Chinese Chemical Letters》2008年第1期95-98,共4页中国化学快报（英文版）

基　　金：This work was supported by the Creative Talented Person＇s Fund of Henan Province （No. [20051126）；Natural Science Foundation of Henan Province （No. 072300460010）；the Fund of Henan Normal University （No. 2006PL06）；the grants from the Henan Key Laboratory for environmental pollution control.

摘　　要：This paper described a new method for the trace determination of fenpropathrin, cyhalothrin and deltamethrin using multiwalled carbon nanotubes （MWCNTs） cartridge. Important parameters, such as the sample pH, eluent and its volume, sample flow rate and sample volume were investigated in detail. The linear ranges, the detection limits, and precisions （R.S.D.） were in the range of 0.1- 40 μg L^-11, 1.34.3 ng L^-1 and 2.3-2.8%, respectively. The performance of the proposed method was validated with real water samples, and the spiked recoveries were in the range of 91.7-117.8%, respectively. The experimental results demonstrated that the proposed method was an excellent alternative for the routine analysis of such pollutants in environmental samples. 2007 Qing Xiang Zhou. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.This paper described a new method for the trace determination of fenpropathrin, cyhalothrin and deltamethrin using multiwalled carbon nanotubes （MWCNTs） cartridge. Important parameters, such as the sample pH, eluent and its volume, sample flow rate and sample volume were investigated in detail. The linear ranges, the detection limits, and precisions （R.S.D.） were in the range of 0.1- 40 μg L^-11, 1.34.3 ng L^-1 and 2.3-2.8%, respectively. The performance of the proposed method was validated with real water samples, and the spiked recoveries were in the range of 91.7-117.8%, respectively. The experimental results demonstrated that the proposed method was an excellent alternative for the routine analysis of such pollutants in environmental samples. 2007 Qing Xiang Zhou. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

关 键 词：Multiwalled carbon nanotubes FENPROPATHRIN CYHALOTHRIN DELTAMETHRIN High performance liquid chromatography 

分 类 号：O657.72[理学—分析化学]