天然物6-正戊基吡喃-2-酮(6PP)的全合成  

A Facile Total Synthesis of 6-Pentyl-α-pyrone

作　　者：张弛[1] 张芳宁 王学超 潘鑫复[1] 

机构地区：[1]兰州大学应用有机化学国家重点实验室,兰州730000

出　　处：《高等学校化学学报》1997年第8期1335-1336,共2页Chemical Journal of Chinese Universities

摘　　要：6-Pentyl-α-pyrone (6PP), a natural product with a number of bioactivies, has been synthesized from furfural in a five steps route. The key step is the epoxidation of 2-furyl-pentylcarbinol (3) with NBS in a mixed solvent system THF and H2O(4: 1). The overall yield is 34%.6-Pentyl-α-pyrone (6PP), a natural product with a number of bioactivies, has been synthesized from furfural in a five steps route. The key step is the epoxidation of 2-furyl-pentylcarbinol (3) with NBS in a mixed solvent system THF and H2O(4: 1). The overall yield is 34%.

关 键 词：全合成 环氧化 6PP 正戊基吡喃酮 天然物 

分 类 号：O629[理学—有机化学]