无扰Polysilane链的热力学函数  

Thermodynamic Functions of Unperturbed Polysilane Chain

作　　者：王治虎 罗孟波[2] 

机构地区：[1]杭州电视大学 [2]杭州大学物理系

出　　处：《科技通报》1997年第4期242-244,共3页Bulletin of Science and Technology

摘　　要：采用旋转异构态模型和二级相互作用近似，计算了无扰Ｐｏｌｙｓｉｌａｎｅ链的内能、自由能和熵。In this paper,we have calculated intrinsic energy, free energy and entropy of the unperturbed polysilane chain by using the rotational isomeric state model and the second order interaction approximation.We have discussed the relations between them and chain length,and temperature.

关 键 词：旋转异构态模型 Polysilane链 热力学函数 

分 类 号：O631.12[理学—高分子化学]