Zinc Borohydride-Ionic Liquid: Stable and Efficient System for Reductive Reaction of Aldehydes with Primary Amines to Corresponding Secondary Amines  

作　　者：NIAN Bao-yi XU Gang WU Jiang-ping YANG Li-rong 

机构地区：[1]Department of Chemistry and Biology Engineering, Sanming University, Sanming 365004, P. R. China [2]College of Material Science and Chemical Engineering, Zhejiang University, Hangzhou 310027, P. R. China

出　　处：《Chemical Research in Chinese Universities》2008年第1期120-122,共3页高等学校化学研究（英文版）

基　　金：National Natural Science Foundation of China(No.20336010);National Basic Research Programme of China(No.2003CB716008)

摘　　要：Ionic liquids（ILs） are attracting much attention in various fields of chemical synthesis, electrochemical applications, liquid-liquid extractions, as well as biotransformations. Among those fields, the application of ILs as the potential green solvent for a wide variety of synthetic processes is an area of intense researches. High yield, high selectivity, and good catalytic charac-teristics have usually been achieved. After the isolation of products, ILs can usually be recovered and recycled many times by simple treating procedures, such as, filtration, extraction, and dryness.Ionic liquids（ILs） are attracting much attention in various fields of chemical synthesis, electrochemical applications, liquid-liquid extractions, as well as biotransformations. Among those fields, the application of ILs as the potential green solvent for a wide variety of synthetic processes is an area of intense researches. High yield, high selectivity, and good catalytic charac-teristics have usually been achieved. After the isolation of products, ILs can usually be recovered and recycled many times by simple treating procedures, such as, filtration, extraction, and dryness.

关 键 词：Ionic liquid Zinc borohydride Reductive arnination BMImBF4 

分 类 号：O627.23[理学—有机化学]