ZrCl4催化苯乙烯的氢胺化反应  

ZrCl_4-catalyzed Hydroamination Reactions of Styrene

作　　者：潘华泉[1] 魏华[2] 李亚红[1] 

机构地区：[1]苏州大学化学化工学院,江苏苏州215123 [2]苏州大学江苏省有机合成重点实验室,江苏苏州215123

出　　处：《合成化学》2008年第1期112-114,共3页Chinese Journal of Synthetic Chemistry

基　　金：江苏省自然科学基金资助项目(BK2005030);教育部留学回国人员基金资助项目(K5109609)

摘　　要：研究了ZrC l4催化的苯乙烯与取代芳香胺的氢胺化反应,讨论了该反应过程中催化剂的用量,反应温度,以及含不同取代基的芳胺对产率的影响。利用该方法合成了5种取代的N-(1-苯基乙基)苯胺,其结构经1H NMR,13C NMR和MS表征。ZrCl4-catalyzed hydroamination reactions of styrene were investigated. Five N-（ 1-phenylethyl） anilines were synthesized via reactions of styrene with different substituted anilines using ZrCl4 as a catalyst. The structures were characterized by ^1 H NMR, ^13 C NMR and MS. The effects of the reaction temperature and the catalyst loadings on the hydroamination reactions were also discussed.

关 键 词：氢胺化反应 ZrCl4 催化 合成 

分 类 号：O627[理学—有机化学]