Baylis-Hillman反应机理研究进展  

Recent Advances in the Study of the Mechanism of Baylis-Hillman Reaction

作　　者：杨春红[1] 樊建芬[1] 乔龙光[1] 

机构地区：[1]苏州大学化学化工学院,苏州215123

出　　处：《有机化学》2008年第2期175-180,共6页Chinese Journal of Organic Chemistry

基　　金：江苏省高校国家级有机化学重点学科培育点经费资助项目

摘　　要：介绍了一种形成碳—碳键的方法——Baylis-Hillman反应,综述了单分子醛、双分子醛反应机理、TiCl4催化机理、不对称诱导机理以及低温效应、溶剂效应、离子液体反应机理的研究进展.A C--C bond forming reaction, namely Baylis-Hillman reaction, is described and the recent progress is reviewed in the study of the reaction mechanisms of the single molecular aldehyde and the double molecular aldehyde, TIC14 catalytic mechanism, asymmetric induction mechanism, temperature and solvent effects as well as the ionic liquid reaction mechanism.

关 键 词：BAYLIS-HILLMAN反应 反应机理 综述 

分 类 号：O643.12[理学—物理化学] O621.3[理学—化学]