铁(Ⅱ)卟啉二胺配合物的合成和表征  

Synthesis and Characterization of Bis(amine) Iron(Ⅱ) Porphyrins

作　　者：钟新华[1] 冯耀宇[2] 黄杰生[1] 申泮文[1] 

机构地区：[1]南开大学化学系,天津300072 [2]天津大学化学工程研究所,天津300072

出　　处：《高等学校化学学报》1997年第3期357-359,共3页Chemical Journal of Chinese Universities

基　　金：天津市21世纪青年科学基金

摘　　要：已报道合成的二价铁叶琳配合物主要集中在毗陡、咪唑、NO等配体上．有机胺虽然是配位化学中一类极为经典的配体，但合成金属叶琳胺类配合物的报道却为数甚少，据我们所知，仅限于Ru[1]、Rh[3]、Os[3]等配合物．迄今还未见合成铁（Ⅱ）卟啉胺类的报道．本文通过引入强氧化...A series of bis(amine) iron(Ⅱ ) porphyrin Fe(Ⅱ )TPP(NH2R)2 complexes (NH2R=PhNH2, C6H11NH2, n-BuNH2, PhCH2NH2, NHMe2; TPP =dianion of meso-tetraphenylporphyrin) were prepared by the reduction of Fe (Ⅲ) porphyrins with the correspondingamine in an antiformin system in air as well as by the sodium borohydride reduction method,respectively. The complexes were charaterized by UV-Vis, IR and elementary analysis, andsome important properties of them were discussed.

关 键 词：铁卟啉 胺 配合物 二胺 

分 类 号：O627.81[理学—有机化学]